Active spreading and hydrothermalism in North Fiji Basin (SW Pacific). Results of Japanese French Cruise Kaiyo 87

The aim of the Japanese-French Kaiyo 87 cruise was the study of the spreading axis in the North Fiji Basin (SW Pacific). A Seabeam and geophysical survey allowed us to define the detailed structure of the active NS spreading axis between 16° and 22° S and its relationships with the left lateral motion of the North Fiji Fracture Zone. Between 21° S and 18°10′ S, the spreading axis trends NS. From 18°10 S to 16°40 S the orientation of the spreading axis changes from NS to 015°. North of 16°40′ S the spreading axis trends 160°. These two 015° and 160° branches converge with the left lateral North Fiji fracture zone around 16°40′ S to define an RRFZ triple junction. Water sampling, dredging and photo TV deep towing give new information concerning the hydrothermal activity along the spreading axis. The discovery of hydrothermal deposits associated with living communities confirms this activity.     

Exploration Indices and Mineral Potential Map of the Kuroko Deposits in Northeast Japan

Abstract. Recent discoveries of seafloor hydrothermal mineralization in submarine volcanic centers of felsic magma in western Pacific island arcs are regarded as modern analogues of Kuroko type deposits. Studies of these deposits and their surrounding geology raised question whether the exploration activity for the Kuroko deposits on land which peaked in the 1960's was adequate or not. However, such an evaluation is not easy because the exploration data are about to be lost as a result of the closure of all the Kuroko mines in the area since 1994.
The Metal Mining Agency of Japan (MMAJ), therefore, decided to compile existing data on about 180 Kuroko deposits and related mineral occurrences in northeast Japan as a new Kuroko database.
This study extends a concept called "exploration indices" which was developed based on a case study of the thoroughly surveyed Hokuroku district to draw a potential map of the Kuroko occurrences for the entire northeast Japan quantitatively with a Geographical Information System (GIS). Effective exploration indices include: 1) distribution of dacitic-rhy-olitic submarine volcanic rocks of the Nishikurosawa and Onnagawa stages, 2) distribution of intrusive rocks of pre- and post-Kuroko horizon, 3) low aeromagnetic anomaly caused by hydrothermal alteration of magnetite, 4) low gravity anomaly which suggests depressions in the basement rocks such as a tectonic basin and/or caldera, and 5) nearby existence of vein type deposits. It is concluded that about 33 % of known Kuroko deposits fall within the high potential zone (score=4 and 5) that occupies only 4 % of the entire northeast Japan arc. The Kuroko potential map is, therefore, useful for limiting the target area for Kuroko type deposits in an island arc setting.     

Phytoplankton dynamics in Lake Biwa during the 20th century: complex responses to climate variation and changes in nutrient status

We examined algal remains and fossil pigments in ²¹⁰Pb-dated sediment cores from Lake Biwa to explore historical changes in the phytoplankton community of the lake over the past 100 years and to identify environmental factors that caused those changes. Fluxes of fossil pigments and algal remains were very low before the 1960s, but increased through the 1960s and 1970s, indicating that the lake had eutrophied in the 20 years since 1960. After 1980, however, fluxes of all fossil pigments and algal remains decreased or stabilized. Redundancy analysis with meteorological and limnological variables explained more than 70% of the variation of these fluxes and showed that the decrease in fluxes of most algal taxa that occurred in the 1980s was related to changes in meteorological variables such as wind velocity, rather than changes in the lake’s trophic state. Sedimentary records of algal remains also revealed that Aulacoseira nipponica, an endemic diatom species that grows in winter, decreased dramatically after 1980, while Fragilaria crotonensis, a cosmopolitan spring diatom species, became dominant. Replacement of one dominant diatom species by another could not be explained simply by changes in the lake trophic state, but was reasonably strongly related with an increase in winter water temperature. These results suggest that the phytoplankton community in Lake Biwa was influenced by changes in local environmental conditions (nutrient loading) through the 1960s and 1970s, but more so by regional (meteorological) and global (climate warming) factors since 1980.     

Mineralogy and Isotope Geochemistry of Active Submarine Hydrothermal Field at Suiyo Seamount, Izu–Bonin Arc, West Pacific Ocean

This report presents mineralogical, geochemical and isotopic data on samples obtained using the Benthic Multi‐coring System (BMS) to drill a submarine hydrothermal deposit developed in a caldera on the summit of the Suiyo Seamount in the Izu–Bonin Island Arc, south of Japan. This deposit is regarded as the first example of Kuroko‐type sulfide mineralization on a volcano at the volcanic front of an island arc. The mineralization and hydrothermal alteration below the 300 × 150‐m area of active venting was investigated to depths of 2–9 m below the sea floor. Drilling beneath the area of active venting recovered a sequence of altered volcanic rocks (dacite lavas, pyroclastic rocks of dacite–rhyolite compositions and pumice) associated with sulfide veining and patches/veins of anhydrite. No massive sulfide was found, however, and the subsea‐floor mineralization to 10 m depth is dominated by anhydrite and clay minerals with some sulfides. Sulfide‐bearing samples contained high Au (up to 42 ppm), Ag (up to 263 ppm), As (up to 1550 ppm), Hg (up to 55 ppm), Sb (up to 772 ppm), and Se (up to 24 ppm). Electron probe microanalyzer indicated that realgar, orpiment, and mimetite were major As‐bearing minerals. The sulfides were also characterized by high Zn (>10%) compared to Cu (<6.3%) and Pb (<0.6%). The δ²⁰²Hg/¹⁹⁸Hg, δ²⁰²Hg/¹⁹⁹Hg and δ²⁰²Hg/²⁰⁰Hg of the sulfide‐bearing dacite samples and a sulfide chimney decreased with increasing Hg/Zn concentration ratio. The variation of the δ²⁰²Hg/¹⁹⁸Hg ranged from ?2.8 to +0.5‰ to relative to S‐HG02027. The large range of these δ²⁰²Hg/¹⁹⁸Hg was greater than might be expected for such a heavy element and may be due to a predominance of kinetic effects. The variation of δ²⁰²Hg/¹⁹⁸Hg of sulfide‐bearing dacite samples suggested that light Hg isotope in the vapor mixed with oxygenated seawater near sea floor during mineralization. Lead isotope ratios of the sulfide were very similar to those of the dacite lava, suggesting that lead is of magmatic origin. The ⁸⁷Sr/⁸⁶Sr ratio (0.70872) of anhydrite was different from that of the dacite lava, and suggests an Sr derivation predominantly from seawater. Hydrothermal alteration of the dacite in the Suiyo hydrothermal field was characterized by Fe‐sulfides, anhydrite, barite, montmorillonite, chlorite/montmorillonite mixed‐layer minerals, mica, and chlorite with little or no feldspar or cristobalite. Hydrothermal clay minerals changed with depth from montmorillonite to chlorite/montmorillonite mixed‐layer minerals to chlorite and mica. Hydrogen isotope ratios of chlorite/montmorillonite and mixed‐layer, mica‐chlorite composites obtained below the active venting sites ranged from ?49 to ?24‰, suggesting seawater as the dominant fluid causing alteration. Oxygen isotope ratios of anhydrite ranged from 9.2 to 10.4‰ and anhydrite formation temperatures were calculated to be 188–207°C. Oxygen isotope ratios ranged from +5.2 to +9.2‰ for montmorillonite, +3.2 to +4.5‰ for chlorite/montmorillonite mixed‐layer minerals, and +2.8 to +3.8‰ in mixtures of chlorite and mica. The formation temperatures of montmorillonite and of the chlorite–mica mixture were 160–250°C and 230–270°C, respectively. The isotope temperatures for clay minerals (220–270°C) and anhydrite (188°C) were significantly lower than the borehole temperature (308.3°C) measured just after the drilling, suggesting that temperature at this site is now higher than when clay minerals and anhydrite were formed.     

Alvin-SeaBeam studies of the Sumisu Rift, Izu-Bonin arc

Bimodal volcanism, normal faulting, rapid sedimentation, and hydrothermal circulation characterize the rifting of the Izu-Bonin arc at 31°N. Analysis of the zigzag pattern, in plan view, of the normal faults that bound Sumisu Rift indicates that the extension direction (080° ± 10°) is orthogonal to the regional trend of the volcanic front. Normal faults divide the rift into an inner rift on the arc side, which is the locus for maximum subsidence and sedimentation, and an outer rift further west. Transfer zones that link opposing master faults and/or rift flank uplifts further subdivide the rift into three segments along strike. Volcanism is concentrated along the ENE-trending transfer zone which separates the northern and central rift segments. The differential motion across the zone is accommodated by interdigitating north-trending normal faults rather than by ENE-trending oblique-slip faults. Volcanism in the outer rift has built 50–700 m high edifices without summit craters whereas in the inner rift it has formed two multi-vent en echelon ridges (the largest is 600 m high and 16 km long). The volcanism is dominantly basaltic, with compositions reflecting mantle sources little influenced by arc components. An elongate rhyolite dome and low-temperature hydrothermal deposits occur at the en echelon step in the larger ridge, which is located at the intersection of the transfer zone with the inner rift. The chimneys, veins, and crusts are composed of silica, barite and iron oxide, and are of similar composition to the ferruginous chert that mantles the Kuroko deposits. A 1.2-km transect of seven alvin heat flow measurements at 30°48.5′N showed that the inner-rift-bounding faults may serve as water recharge zones, but that they are not necessarily areas of focussed hydrothermal outflow, which instead occurs through the thick basin sediments. The rift basin and arc margin sediments are probably dominated by permeable rhyolitic pumice and ash erupted from submarine arc calderas such as Sumisu and South Sumisu volcanoes.     

Liquid Immiscibility of Boninite in Xiangcheng, Southwestern China, and Its implication to Genetic Relationship between Boninite and Komatiitic Basalt

Boninitic rocks and associated high-magnesian basalt and high-iron tholeiite in the Xiangcheng area constitute the basal horizon of the arc volcanic sequence in the Triassic Yidun Island-Arc, southwestern China. The boninite occurs as pillow, massive and ocellar lavas; the last one possesses well-developed globular structure and alternates with the former two. The boninite is characterized by the absence of phenocrysts of olivine and low-Ca pyroxenes and by low CaO/Al2O3 ratios (<0.67) and high Cr (>1000 ppm) and Ni (>250 ppm). The normalized abundance patterns (NAP) of trace elements to primitive mantle are similar to the NAP of low-Ca modern boninites and SHMB in the Archaean and Proterozoic.As a mechanism of ocellar texture, liquid immiscibility in boninite is supported by the following lines of evidence: (a) sharp contact between ocelli and matrix, (b) constant volumetric ratios of ocelli/matrix and common coalescence of ocelli in ocellar rocks, (c) identical micro-spinifex textures and mineral asse     

Partition of cadmium and manganese between coexisting sphalerite and galena from some Japanese epithermal deposits

Sphalerites from Japanese epithermal Pb-Zn vein-type deposits, namely, Yatani, Oizumi and Hosokura, contain 2900–3400 ppm cadmium and 760–2100 ppm manganese. And galenas from the same deposits contain cadmium and manganese 19.2–26.9 ppm and 7.8–218.3 ppm, respectively. The temperatures, evaluated from the partition of cadmium between coexisting sphalerite and galena, are consistent within a total range of 150°C at maximum within an individual deposit. No systematic change with depth can be observed at the Shoko-hi vein, Hosokura mine and Hompi vein, Yatani mine. In several samples, the temperatures obtained from the partition of cadmium have been compared with those obtained from sulfur isotope fractionations. Iron content in sphalerite coexisting with pyrite indicates that the deposition of ore minerals at these deposits may have taken place from ore-forming solutions in which H₂S or HS^– was the predominant dissolved sulfur species, and the solutions may have been free from in situ oxidation or reduction.     

Mineralogical aspects of the Kuroko deposits in Japan and their implications

The most remarkable difference in mineralogy of the Kuroko deposits in Japan is shown in their mineral assemblages of wall-rock alteration. They can be divided into three types, namely: (I)kaolinite-pyrophyllite-diaspore type, (II)sericite-chlorite type, and (III)sericite-chlorite-carbonate type. The assemblage of sulfide minerals characteristically differs in each type of the deposits. The distribution of the Kuroko deposits, classified according to the three types, shows regional zoning. At the waning stage of the deposition of black ore of type (II), related mineral assemblages of both types (I) and (III) are found locally. Slight increase in fugacities of oxygen and sulfur, and decrease in temperature took place during the formation of a deposit. Regional zoning of the assemblage of alteration minerals, therefore, corresponds to slight differences in the processes of ore formation during deposition.